Pro-aromatic bisphenaleno-thieno[3,2-b]thiophene versus anti-aromatic bisindeno-thieno[3,2-b]thiophene: different ground-state properties and applications in field-effect transistors.

نویسندگان

  • Xueliang Shi
  • Sangsu Lee
  • Minjung Son
  • Bin Zheng
  • Jingjing Chang
  • Linzhi Jing
  • Kuo-Wei Huang
  • Dongho Kim
  • Chunyan Chi
چکیده

A pro-aromatic bisphenaleno-thieno[3,2-b]thiophene (BPT-TIPS) was synthesized and compared with an anti-aromatic bisindeno-thieno[3,2-b]thiophene (S2-TIPS). BPT-TIPS showed larger diradical character, stronger absorption, longer excited state lifetime and better redox amphotericity than S2-TIPS.

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عنوان ژورنال:
  • Chemical communications

دوره 51 67  شماره 

صفحات  -

تاریخ انتشار 2015